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The pH factor is the most important factor influencing scale formation and the corrosive tendencies of boiler water. The pH should be maintained between a minimum of 10.5 and a maximum of 11.0 to prevent acidic corrosion of boiler tubes and plates, and to provide for the precipitation of scale forming salts before scale is deposited.
Jan 01, 2011 · The model demonstrated that a 34% increase in federate was required to elevate the pH of the LP Evaporator to 9.3 pH. In fact, recent plant experience at EcoEléctrica shows that under certain plant conditions (i.e. low loads), it is very difficult if not impossible to keep the LP Evaporator liquid pH …
Jan 27, 2013 · Inexplicable pH drop in boiler blowdown water. A discussion started in 2004 but continuing through 2019. 2004. Q. This question pertains to drop in pH of blowdown water of a low pressure steam boiler. In one of the waste heat recovery boilers, (operates at 180 °C), pH of the blow down water drops to 5 and even 4.
Jun 24, 2014 · It comes into play with steam boilers because a pH between 7 and 9 (slightly alkaline) is just right. If the pH is lower than that, the water will start eating the pipes. If it's higher than that, the water won't corrode metal, but it may begin to foam, and that's not good. Hold that thought for a moment.
An anti-corrosive agent for boilers, which comprises diethanolamine, can additionally contain a deoxidizer such as hydrazine, 1-aminopyrrolidine, N,N-diethylhydroxylamine, ascorbic acid and a salt thereof and another anti-corrosive agent comprising a neutralizing amine, and can be added to mainly boiler water having a superheater and a steam turbine.
It ranges from 0 to 14. A pH of 7 is neutral. A pH less than 7 is acidic, and a pH greater than 7 is basic (alkaline). Each whole pH value below 7 is ten times more acidic than the next higher value. For example, a pH of 4 is ten times more acidic than a pH of 5 and 100 times (10 times 10) more acidic than a pH …
Jun 01, 2017 · Idle boilers not properly stored will corrode until either the oxygen has been used or the boiler returned to service. The purity of the makeup water and any pH control agents …
Understanding alkalinity in steam and cooling systems. - Environmenta…
It ranges from 0 to 14. A pH of 7 is neutral. A pH less than 7 is acidic, and a pH greater than 7 is basic (alkaline). Each whole pH value below 7 is ten times more acidic than the next higher value. For example, a pH of 4 is ten times more acidic than a pH of 5 and 100 times (10 times 10) more acidic than a pH of 6.
Jul 10, 2017 · pH adjustment to get the pH up to at least 7.0 at the discharges of all steam-condensing units and within the desired range elsewhere through the return system. To keep the dissolved iron and copper at very low levels, i.e. well below 0.1 ppm. To maintain low corrosion rates on corrosion coupons installed in steam condensing and return systems.
The safe pH range for steam boilers is between 8.5pH & 12.7pH, whilst the recommended level is between 10.5pH & 12.0pH. Boiler water with a pH of 10.5 contributes 12.6mg/l towards the boiler TDS, whilst at a pH of 12.0 it increases to 400mg/l and at 12.5pH the value is 1264.9 mg/l a 100 fold increase.
pH will be slightly lower than that of the feedwater. The other inherent characteristic of ammonia (and other amines) is its lower ionic dissociation rate at higher tem-peratures. Consequently, the actual, local pH decreases with an increase in the fluid temperature as illustrated in Figure 2. This aspect of the ammonia pH/temperature
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Chemical control - Anti-foaming agents may be added to the boiler water. These operate by breaking down the foam bubbles. However, these agents are not effective when treating foams caused by suspended solids. Control of TDS - A balance has to be found between:-A high TDS level with its attendant economy of operation.
Not only will this help to passify the metal, it will also prevent oxygen pitting. Proper boiler water pH should be close to 10.0 at the beginning of the run and no higher than 12.0 at the end. For the best magnetite layer formation, a pH of 11.0 to 12.0 is usually recommended.
The normal approach to treating systems with these amines is to feed sufficient quantity to neutralize the carbon dioxide and then provide small additional amounts to buffer the pH to 8.5 or 9.0. At this pH, continued preservation of the magnetite film (boiler metal) is also achieved. It is also implied that corrosion will not exist at a pH>8.0
concentration in boilers water as shown in fig. 1. Figure 1: Phosphate treatment systems used in boilers . The most popular treatment for low pressure boilers (< 600 psi) is dosing of tri-sodium phosphate (TSP), it reacts with water at high temperature and gives sodium hydroxide to increase boilers water pH as shown in equation (1).
"Operate the boiler at its maximum design pressure" is a common saying among boiler designers. But too often, this rule is not followed when energy cost reductions are needed. During periods of low steam demand, or when all the use points require pressure-reducing stations, boilers are often operated at substantially less than design pressure.